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A corrosion inhibitor is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy.〔Hubert Gräfen, Elmar-Manfred Horn, Hartmut Schlecker, Helmut Schindler "Corrosion" Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH: Weinheim, 2002. 〕 The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime. A common mechanism for inhibiting corrosion involves formation of a coating, often a passivation layer, which prevents access of the corrosive substance to the metal. Permanent treatments such as chrome plating are not generally considered inhibitors, however. Instead corrosion inhibitors are ''additives'' to the fluids that surround the metal or related object. ==Corrosion inhibitors and their role== The nature of the corrosive inhibitor depends on (i) the material being protected, which are most commonly metal objects, and (ii) on the corrosive agent(s) to be neutralized. The corrosive agents are generally oxygen, hydrogen sulfide, and carbon dioxide. Oxygen is generally removed by reductive inhibitors such as amines and hydrazines: :O2 + N2H4 → 2 H2O + N2 In this example, hydrazine converts oxygen, a common corrosive agent, to water, which is generally benign. Related inhibitors of oxygen corrosion are hexamine, phenylenediamine, and dimethylethanolamine, and their derivatives. Antioxidants such as sulfite and ascorbic acid are sometimes used. Some corrosion inhibitors form a passivating coating on the surface by chemisorption. Benzotriazole is one such species used to protect copper. For lubrication, zinc dithiophosphates are common - they deposit sulfide on surfaces. The suitability of any given chemical for a task in hand depends on many factors, including their operating temperature. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Corrosion inhibitor」の詳細全文を読む スポンサード リンク
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